POLYPHENOLS IN FRUITS AND GRAPE

Aronia (Aronia melanocarpa Michx) – Dominant chokeberry anthocyanins are 3-galactoside cianidin and cianidin 3-arabinoside. The concentration of flavonols in chokeberry exceed 71 mg / g fresh weight. Flavanones eriodictyol 7-O-β-glucuronide along with rare flavonol quercetin 3-vicianosidom and quercetin 3-robinobiosidom quercetin glycosides and other proven in chokeberry Slimestad research associates and the 2005th.

Avocado (Persea americana Mill) – Avocado is a tropical fruit, rich in polyphenolic compounds such as:   brown, hlorogenska, coumarin acid, catechin, epicatechin.

Banana (Musa acuminata) This fruit proved the presence of tannin, gallic acid, catechin, anthocyanins-3-rutinoside, cianidin-3-rutinoside, petunidin-3-rutinoside, pelargonidin-3-rutinoside, peonidin-3-rutinoside and malvidin-3-rutinoside.

Bilberry (Vaccinium myrtillus L) – Blueberries are rich in anthocyanins, whose amount varies from 300-600 mg/100g. Effect on improving the nutritional value of foods by preventing oxidation of lipids and proteins of food products.

Cranberry (Vaccinium macrocarpa L) – Cranberries are anthocyans: cianidin-3-gala tozid, cianidin-3-glucozid and cianidin-3-arabinoside. Fresh cranberries, juice, frozen or dried as a natural antibiotic.

Black currant (Ribes nigrum L.) – Black currant contains 1.253 to 6.166 mg / g total anthocyanins. Proven pigments are Delphinidin-glucozid, Delphinidin-rutinosid, cianidin-glucozid, cianidin-rutinoside.

Blood orange (Citrus sinensis L.) The species of the genus Citrus Flavanones characteristic polyphenols, primarily hesperetin and naringinenin in the form of glycosides.

Goji (Lycium barbarum L) – Goji contains bioflavonoids, anthocyanins, lutein. The presence of these components and their relationship led to the fruit on top of the ORAC scale (Oxygen Radical Absorbance Capacity – Scale, which measures the antioxidant capacity or antioxidant value of foods). According to this scale goji berries have 25 300 units, and these first fruits, which are normally considered a strong antioxidant, pomegranate is the „only“ 12 500 units.

Grapes (Vitis vinifera L) – varieties of grapes are a rich source of flavonoids, polyphenols, 70% is located in the seed, and about 30% in the skin. Polyphenols have been identified in the cluster: flavan-3-ols (catechin and epicatechin), procijanidini, tannins, flavonols (quercetin, myricetin), antocijanidini. The content of anthocyanins in grapes varies from 12 to 30 mg / g.

Guava (Psidium guajava L) – polyphenolic compounds of guava are sumorin-3-O-liksozid, morin-3-O-arabinoside, quercetin, quercetin-3-O-arabinoside, leukoantocijanidin, ellagic acid.

Kiwifruit (Actinidia deliciosa A. Chev.) The results showed that the predominant phenolic compound kiwi hidroksicimetna acid, flavonols and flavan 3-ol epicatechin.

Blackberry (Rubus fruticosus agg.) The blackberry extract proved the following anthocyanins: cijanidin-3-glucoside, cijanidin-3-galactoside, cijanidin-3-arabinose, pelargonidin-3-glucoside; cijanidin-3-ksiluloza; malvidin-3- glucoside. Cijanidin-3-glucoside is the dominant pigment in berries.

Longan (Euphoria longan Lamk) – Longan is an exotic fruit, which contains polyphenolic compounds. Dominant polyphenolic compounds were: gallic and ellagic acid and elagintanin.

Raspberry ( Rubus idaeus L) – Malina is a highly valuable nutritionally because of the rich content of various antioxidants. The antioxidant activity of raspberries is 50% higher antioxidant activity than strawberries, 10 times higher than the tomatoes and 3 times higher than the kiwi. About 25% belongs to the polyphenol antioxidant activity such as quercetin, kaempferol, cijanidin-3-glukozilrutinozid, cijanidin-3-rutinoside and pelargonidin glycoside. These compounds give intense red raspberry.

Mango (Mangifera indica L) – According to the results of research flavonols manga are dominant Q 3-galactozid (22.1 mg / kgs), Q 3-glucozid (16 mg / kg) and Q 3-arabinoside (5 mg / kg.)

Mangosteen (Garcinia mangostana L) – This fruit is referred to as medicinal fruit of the gods. Mangosteen contains a large group of xanthones, flavonoids with strong antioxidant activity. Of the 200 known xanthones nearly 50 are found in mangosteen. The main fruit of this xanthones are alpha-, beta-, gamma-and beta-methoxy-mangostin. Quantitative dominantain alpha-mangostin. Mangosteen contains, in addition to xanthones and anthocyanins, stilbene and tannins. The concentration of total anthocyanins in the mangosteen is 25.9 to 63.9 mg/100g.

Olive (Olea europaea) – Olives contain polyphenols hydroxytyrosol and sip a tea acid. HPLC in olive oil was confirmed in the presence of low concentrations hidrokisitirozila, tirozila, lignans. GC-MS method proved the presence of vanilla acid, p-hidrokisbenzojeve, p-coumarin, o-coumarin acid.

Pomegranate (Punica granatum L) Contains elagintanin 3,3 ‘-di-O-metilelaginsku acid, 3,3′, 4′-tri-O – metilelaginsku acid phenethyl-rutinoside. New dimerik gallic acid, named after humarain, was isolated from the stem bark of pomegranate.

Noni (Morinda citrifolia L ) – The fruit of the noni fruit belongs to a group of 80 medicinal plants, which are today considered the most effective medicinal plant group on the planet. This tropical fruits contain bioflavonoids catechin and epicatechin-, tannins.

Papaya (Carica papaya L) – Papaya contains myrcene, ocimen, phellandrene, terpinene, a dried leaf 0.25 mg / g tea acids, 0.33 mg / g p-kuumarinske acid and 0.11 mg / g protokatehinske kiselinue. The concentration of quercetin was kempferola and 0.04 mg / g.

Plum (Prunus domestica L) – Color plum fruit epidermis may be the green-yellow through red and blue, different shades of blue to blue-violet. Shades of blue, red and blue colors and plavoljubičaste are conditioned by the type and amount of anthocyanins . Today is one of the goals of breeding to create new varieties of plums with dark fruit epidermis. Plums contain different varieties cijanidin-3-glucoside and cijanidin-3-rutinoside, peonidin-3-glucoside and peonidin-3-rutinoside. Cevallos-Casals et al., (2002) found that the content of anthocyanins in the fruit selection of 13 plums ranged from 44.1 to 231.29 mg / 100 g mezokarpa fresh, calculated on cijanidin-3-glucoside.

The grapevine leaf (Vitis vinifera L) – vine leaves can be considered a good source of polyphenolic compounds . The research results confirm that the extracts of leaves and vines extremely rich phenolic compounds. HPLC analysis showed the presence of flavonoid and stilbene. Among the polyphenols from the group identified as stilbene resveratrol monomers (cis-and trans-resveratrol) and resveratrol derivatives (astringin and piceid / isorhapontin).

Cherry (Prunus cerasus L) – Cherries are a rich source of atocijana. The concentration of these pigments depends on the variety, cultivation methods, climate, climate and other factors.

Author: MPG71

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CONTENT OF TOTAL FLAVONOLS IN THE DIFFERENT FRUITS

Fruit Concentration (mg/1kg)
Black currant (Ribes nigrum Öjebyn)

115

Red currant (Ribes nigrum Vertti)

32

Red currant (Ribes × pallidum Red Polish)

9

White currant (Ribes x pallidum White Polish)

7

Yellow Gooseberry (Ribes uva-crispa)

34

Cven Gooseberry (Ribes uva-crispa)

41

Swamp blueberry (Vaccinium uliginosum-wild)

184

Red Currant (Vaccinium vitis-idaea-wild)

74, 15

Cranberry (Vaccinium oxycoccos-wild)

157, 26

Bilberry (Vaccinium myrtillus-wild)

43, 51

Northern Bilberry (Vaccinium corymbosum Northblue)

40

Strawberry (Fragaria × ananassa Senga Sengana)

15

Strawberry Jonsok (Fragaria x ananassa Jonsok)

12

Aronia (Aronia mitschurinii Viking)

89

Rowan (Sorbus aucuparia-wild)

63

Sweet rowan (Grataegosorbus mitschurinii Granatnaja)

85

Raspberry (Rubus idaeus Ottawa)

8

Muskoka raspberry (Rubus idaeus Muskoka)

8

Wild raspberry (Rubus idaeus-wild)

6

Swamp raspberry (Rubus chamaemorus-wild)

6, 6

North blackberry (Rubus arcticus Pima and MESP)

31

Source: Hakkinen SH, Karenlampi SO, Heinonen IM, Mykkanen HM, Torronen AR., Content of the flavonols quercetin, myricetin, kaempferol and edible berries in 25, J Agric Food Chem 1999, (6) :2274-9.

Author: MPG71

CONTENT QUERCETIN, MYRICETIN AND KEMPEFEROL IN FRUIT

Fruit

Concentration

(Mg/1kg fresh fruit)

Quercetin Myricetin Kaempferol
Black Currant 44 71
White Currant 7
Yellow Gooseberry 18 16
Gooseberry red 22 19
Blueberry Marsh 158 26
Red Currant 74, 146
Cranberry 83, 121 74, 142
Blueberry 29 30 14, 21
North Blue Blueberry 17 23
Strawberry 7 8
Strawberry Jonsok 7 5
Aronia 89
Rowan 63
Sweet rowan 85
Raspberry 8
Wild Raspberry 6
Raspberry wetland 6, 6
Blackberry northern 31

Source: Hakkinen SH, Karenlampi SO, Heinonen IM, Mykkanen HM, Torronen AR., Content of the flavonols quercetin, myricetin, kaempferol and edible berries in 25, J Agric Food Chem 1999, (6) :2274-9.

Author: MPG71

PHENOLIC ACIDS

Phenolic acids are a large group of phenolic compounds, which are found in foods of plant origin. Phenolic acids have different functions in plants including nutrient assimilation, protein synthesis, enzyme activity and photosynthesis. Share on derivatives cimetne and hydroxybenzoic acid. Most abundant hydroxy benzoic acid derivatives are phydroxybenzoates, vanilla, gallic, protokatehin and ellagic acid.

Protokatehinska acid is present in plants of different families, and gallic acid is a component of many substances taninskih (galotanini). For the aromatic nucleus can bind and methoxy groups, as is the case with vanilla acids.

The molecules of gallic acid can build a new CC link, which produces heksahidroksidifenska acid arises from the elimination of ellagic acid.

Phenolic acidsare known antioxidants because of the ability to turn hydrogen or an electron and because their stable radicals interemedijeri prevent oxidation of the various components, particularly fatty acids and oils.

Hydroxy derivatives of benzoic acid and cimetne are present in foods of plant origin (fruits, vegetables, cereals). They are found in all parts of plants (roots, stems, leaves, seeds). In different parts of plants are different concentrations of phenolic acids. In addition, in various stages of development are present in different plant phenolic acids. Growth conditions, such as temperature, affect the content of phenolic acids.

A small part of the phenolic acids in free form while most related ester, ether or acetal bond with structural components of plants (cellulose, lignin and protein) or with small organic molecules (glucose, kvinska, maleic and tartaric acid) and other natural products ( terpenes).

Hydroxybenzoic acids in free form and esterifikovanoj proven only in some higher plants. Cimetne acid (p-kumarna, tea, and ferulna sinapinska acid) are represented in more than hidroksibenzovu acid. Tea and acid forming kininska hlorogensku acid which is found in many fruits, and higher concentrations of coffee (one cup contains 70-350 mg hlorogenske acid). Cimetna acid is found in all parts of the fruit, and the highest content was found in the outer layer of ripe fruit. Brown acid is isolated from coffee. In a free and esterified form is the most zastupljna phenolic acids and is 75 to 100% of the total content of acid derivatives cimetne in fruit. The most important source of acid ferulne the grains in which the dominant phenolic acids.

Author: MPG71